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Substances authorised in Europe

Substances authorised in Europe

Updated on 15/10/2026

Official sources automatically checked on 20/10/2026.

Which substances can be freely used to make your own herbal preparation in Europe? This page lists the basic substances approved by the European Union, French “natural preparations of low concern” (PNPP), their equivalents in other countries, substances currently under review or rejected, and links to the recipes in this collection. This document was updated on October 13, 2026; it is not a substitute for legal advice.

The Essentials in 4 Points

  • In the European Union, a preparation that claims to protect plants against pests is considered a plant protection product: it must be authorized (Regulation (EC) No. 1107/2009).
  • Exception: “basic substances” (Article 23 of the same regulation). Once approved for the entire EU, they may be used without a product authorization, but only for the uses, doses, and formulations described in their review report.
  • "PNPPs" are a French classification: they refer to either basic substances or natural substances used as biostimulants (SNUBs), which claim only to be natural and to have a biostimulant effect.
  • A homemade preparation is covered only if ALL of its ingredients appear on these lists and if it is prepared and used in accordance with the conditions listed there.

The 28 basic substances approved in the EU

List as of October 13, 2026 (Part C of the Annex to Implementing Regulation (EU) No. 540/2011). Approvals are not time-limited. Specific uses, doses, and crops are listed in the review report for each substance (EU Pesticide Database).

SubstanceScientific/Chemical NameApproval RegulationsUses Approved by Regulation (Summary)Organic Farming
Field horsetailField horsetailRegulation (EU) No. 462/2014Downy Mildew and Powdery Mildew: Vineyards, Orchards, and Vegetable FarmsYes
Chitosan hydrochlorideChitosan hydrochlorideRegulation (EU) No. 563/2014Boosting Natural Defenses: Grains, Vines, and Vegetable CropsYes
SucroseSucroseRegulation (EU) No. 916/2014Boosting natural defenses; grapevines (downy mildew, flavescence dorée leafhopper)Yes
Calcium hydroxideCa(OH)₂Regulation (EU) 2015/762Canker (Nectria galligena) on Fruit TreesYes
VinegarAcetic acid ≤ 10%Regulation (EU) 2015/1108Disinfection of tools and seeds; weed controlYes
LecithinsLecithins (E322)Regulation (EU) 2015/1116Powdery Mildew: Vineyards, Fruit Tree Cultivation, Vegetable FarmingYes
Willow barkSalix spp. barkRegulation (EU) 2015/1107Downy mildew and powdery mildew: grapevines, apple trees, peach treesYes
FructoseFructoseRegulation (EU) 2015/1392Boosting natural defenses; grapevines (downy mildew, leafhoppers)Yes
Sodium hydrogen carbonateNaHCO₃Regulation (EU) 2015/2069 (to be confirmed)Powdery Mildew: Vineyards, Fruit Tree Cultivation, Vegetable FarmingYes
WheyWheyRegulation (EU) 2016/560Powdery mildew; tool disinfectionYes
Diammonium phosphate(NH₄)₂HPO₄Regulation (EU) 2016/548Bait in traps (fruit flies)Yes (traps)
Sunflower oilSunflower oilRegulation (EU) 2016/1978Powdery Mildew on TomatoesYes
Clay coalCharcoal + bentoniteRegulation (EU) 2017/428Vines: EscaNo
Stinging NettleUrtica spp.Regulation (EU) 2017/419Insects, mites, and fungi: vineyards, vegetable farming, and fruit tree cultivation (according to the review report)Yes
Hydrogen peroxideH₂O₂Regulation (EU) 2017/409Disinfection of Tools and SurfacesYes
Sodium chlorideNaCl (food grade)Regulation (EU) 2017/1529Vineyards (limited use, 6 kg/ha/year); mushroom farmsYes
BeerBeerRegulation (EU) 2017/2090Slug and Snail TrapsYes
Mustard Seed PowderMustard Seed PowderRegulation (EU) 2017/2066Wheat Seed Treatment (Rotten Seeds)Yes
Talc E553bHydrated magnesium silicateRegulation (EU) 2018/691Physical barriers (pear psyllid, sunscald); under reviewYes
Onion oilAllium cepa oilRegulation (EU) 2018/1295Repellent (carrot fly), dispensersYes
L-cysteineL-cysteine (E920)Regulation (EU) 2020/642Exact usage to be confirmedYes
Cow's milkCow's milkRegulation (EU) 2020/1004Powdery mildew (vegetable crops), to be confirmedYes
Onion bulb extractAllium cepa L. bulb extractRegulation (EU) 2021/81Vegetable farming and arboriculture (uses to be confirmed)Yes
ChitosanChitosan (≥ 85%)Regulation (EU) 2022/456Boosting Natural Defenses: Vines, Grains, and Vegetable CropsTo be confirmed
Magnesium hydroxideMg(OH)₂, E528Regulation (EU) 2024/836Grapevine: downy mildew, powdery mildew, black rot (≤ 3.5 kg/ha, 1 application per year)No
Sainfoin (pellets)Onobrychis viciifoliaRegulation (EU) 2024/1768Grapevine: Xiphinema index nematodeNo
Processed scallionsAllium fistulosum L.Regulation (EU) 2024/2878Usage to be confirmedTo be confirmed
Grape Seed ExtractVitis vinifera L. seed extractRegulation (EU) 2025/96Downy mildew of grapevines; apple trees, lettuce, potatoesTo be confirmed

In organic farming, Annex I of Implementing Regulation (EU) 2021/1165 permits the specifically listed basic substances and, more generally, those that are foodstuffs of plant or animal origin.

Eligible: Applications currently under review

SubstanceSubjectWhat is the current status of the case?
WaterApproval as a base substanceConsultation with Member States (October 2025)
Sodium hypochlorite (< 1%)Seed TreatmentNo qualified majority (December 2025); issue put on hold
Ethyl formatePost-harvest fumigationApplication filed (March 2025)
OzoneApprovalDiscussion (May 2025), Member States divided
Potassium sorbateUse against nematodesNew Application (July 2025)
HorsetailPost-harvest extensionFiled (March 2025)
Chitosan hydrochlorideApplication: rapeseed, grapevines, turfEFSA Reports (June 2026)
Sodium chlorideExtension: Ragweed Weed Control (roads, railways)Scheduled vote (September 2026)
Talc E553bReview of ApprovalRisk of withdrawal (proposed carcinogen classification)

Source: Minutes of the European Commission’s Standing Committee (SCoPAFF, Plant Protection Products Section), March 2025 through September 2026. A simplification proposal (“omnibus,” COM(2025) 1030) calls for the rewriting of Article 23.

Rejected or set aside

SubstanceDecision
Chili Pepper Oleoresin (Capsicum)Vote in favor of rejection (May 2026)
Quassia amara wood extractProposed Non-Approval (2026)
Yeast-Fermented Stinging Nettle (New Recipe)Rejection of the extension put to a vote (September 2026)
Burdock (Arctium lappa)Rejected (RE (EU) 2015/2082)
Yarrow, wormwood, mugwort, comfrey, tansy, propolis, rhubarb, soapwort, savory, and oregano (essential oils), paprika, pine tar, vine shoot tannins, CO₂Candidates Rejected by the Commission (2022 List)

A homemade preparation made from these substances is not covered under the basic substances program.

France: the PNPPs

Article L.253-1 of the Rural Code distinguishes between two categories of PNPPs: those composed of basic substances (see the European list above) and those composed exclusively of natural substances used as biostimulants (SNUBs). SNUBs are classified as fertilizers: their labeling may only highlight their natural character and their use as biostimulants.

Permitted processes: no processing or manual, mechanical, or gravitational methods; dissolution or extraction with water or alcohol; steam distillation; heating to remove water. Examples: fermentation (liquid manure), maceration, decoction, infusion, pressing. Excluded: freeze-drying, atomization, ultrasound, microwaves.

Who is authorized as a SNUB? The list is open:

  • Any edible part of a plant used for human or animal consumption (fruits, vegetables, seeds, seaweed), whether fresh, dried, or frozen—specifications set forth in the decree of June 14, 2021. Approximately 1,200 species, according to ITAB.
  • The 148 medicinal plants that are available over the counter (Article D.4211-11 of the Public Health Code).
  • Field horsetail (above-ground parts, decoction, or infusion) and willow (bark and stems, infusion), added by decree in 2022.

Requirements: Keep the registration form on file for 3 years; note the expiration date; do not apply within 3 days of harvest for unheated preparations; keep essential oils at least 5 m away from a water source. Plants listed in the EFSA Compendium (e.g., comfrey): document that the dose is safe.

The 148 over-the-counter plants (by usage category)

  • Herbs: basil, marjoram, oregano, rosemary, thyme, wild thyme, garden and mountain savory, sage (common, Spanish, clary, and three-lobed), bay leaf, tarragon, peppermint and spearmint, lemon balm, lemon verbena, balsam
  • Lavender varieties: true lavender, spike lavender, stoechas lavender, lavandin grosso
  • Apiaceae: dill, green anise, caraway, ajwain, cilantro, bitter and sweet fennel, angelica (fruit), lovage, marsh angelica
  • Spices: star anise, Ceylon and Chinese cinnamon, cardamom, cloves, nutmeg and mace, ginger, turmeric, temoe-lawacq, large and small galangal, cayenne pepper, saffron, fenugreek, reed mustard, horseradish, juniper, lemongrass
  • Wild Plants and Herbal Teas: dioecious and stinging nettles, white deadnettle, yarrow, lady's mantle, woodruff, greater burdock, pimpernel, mullein, borage, heather, Roman chamomile, feverfew, small centaury, chicory, dandelion, couch grass, cowbane, poppy, nasturtium, garlic mustard, sea fennel, elecampane, yellow gentian, marshmallow, mallow, hollyhock, hops, ground ivy, meadowsweet, wild pansy, violet, meadowsweet, bramble, Chinese gooseberry, linden, ash trees, Scots pine (bud), eucalyptus, myrtle, olive tree (leaf), red vine (leaf), roses, rosehip
  • Fruits, vegetables, grains, seeds: garlic, black radish, oats, wheat (bran), rye, flax, sweet almond, squash and pumpkin (seeds), black currant, blueberry, hawthorn, fig, apple, plum, cherry stems, black elderberry, jujube, bitter and sweet orange, papaya, tamarind, sugarcane, hibiscus, ambrette, safflower
  • Stimulating and exotic plants: tea, mate, kola, guarana, ginseng, eleuthero, licorice, aloe (mucilage)
  • Seaweed and lichen: agar-agar, ascophyllum, carrageenan, fucus, kelp, Iceland moss
  • Gums: gum arabic, tragacanth, karaya, guar, carob, locust bean, copahu balm

This is a tentative grouping; the official numbered list is set forth in Article D.4211-11 of the Public Health Code.

France: What SNUB Might Become

  • No specific processing required: any edible part of the plant prepared in accordance with the 2021 specifications.
  • Non-food plants or non-plant substances: application submitted to the Ministry of Agriculture, evaluation by ANSES, followed by a ministerial order (e.g., horsetail and willow approved in 2022; leonardite rejected in 2023).
  • Individual authorization: specifically for essential oils not included in the specifications.
  • Excluded: GMO plants, contaminated plants, plants exceeding residue limits, and essential oils already approved as active ingredients.

Elsewhere in Europe

Italy — “plant growth promoters, enhancers of plants’ natural defenses” (Ministerial Decree No. 229771 of May 20, 2022, Annex 2), 15 categories:

  1. Propolis (aqueous, hydroalcoholic, or oily extract)
  2. Rock powder
  3. Sodium bicarbonate (≥ 99.5%)
  4. Silica gel
  5. Biodynamic preparations
  6. Edible vegetable oils
  7. Lecithin
  8. Wine vinegar or fruit vinegar
  9. Soft soap or Marseille soap
  10. Quicklime
  11. Chestnut extract rich in tannins
  12. Ascorbic acid in solution (post-harvest)
  13. Ozonated vegetable oil
  14. Glycolic extract of flavonoids
  15. Inactivated Saccharomyces cerevisiae yeast
  • Germany: Plant fortifiers (Pflanzenstärkungsmittel) must be notified to the BVL before they are placed on the market; the BVL publishes a list that is updated monthly.
  • Spain: The “otros medios de defensa fitosanitaria” regime was significantly restricted in 2014 (Royal Decree 951/2014); there is no equivalent to PNPPs. These products are classified as either plant protection products or fertilizers/biostimulants.
  • Portugal: Plant extracts and oils used to protect crops are plant protection products that require authorization (DGAV, 2023).
  • Belgium and other countries: general European law (basic substances for plant protection; Regulation (EU) 2019/1009 on biostimulants).

Regulatory updates

  • 15/10/2026 — UE — EFSA, pesticides (avis et rapports)
    143rd Plenary meeting of the Panel on Plant Protection Products and their Residues (PPR) - Open for observers … Overall conclusions on the application for approval of chitosan hydrochloride as a basic substance for extension of use in plant protection for oilseed rape crops and potatoes

Authorised recipes by country

Choose a country or territory to see the bio-preparation recipes authorised there, with a summary of the legal framework and the official texts.

See the 22 countries →

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The recipes in this collection and their status

Each recipe shows its regulatory status. Open a recipe to see the details and official texts.

Authorised (40)

Authorised under conditions (13)

Not authorised in the EU as home-made preparations (8)

Sources

This document is a summary based on official texts and institutional sources as of October 13, 2026. It does not constitute legal advice or a recommendation for use. Always check the substance review report and the regulations in your country before preparing or using the substance.